How to Learn Moves as a Blue Mage
        
        When you defeat an enemy after it has used that spell, you have a chance of learning it. Doing instances either premade with no Undersize options selected or with both Undersize and Level Sync options make the spell a 100% learn rate. Spell chances in the open world or Masked Carnivale are RNG based on the number of stars for that spell.      
If you die before the enemy does you will not learn the spell. You must be alive as it dies in order to learn the spell. Killing an enemy with Self-destruct or Final Sting will result in failure to learn the spell.
 Water Cannon
              Water Cannon Flame Thrower
              Flame ThrowerRaid
Einhander from The Keeper of the Lake
Magitek Gunship from The Keeper of the Lake
Omega from Alphascape V3.0
 Aqua Breath
              Aqua BreathLeviathan from The Whorleater (Hard), The Whorleater (Extreme)
Ultros from Stage 20 Masked Carnivale - Miss Typhon
 Flying Frenzy
              Flying FrenzyDungeon
Zu (2nd Boss) from Pharos Sirius (Kill 2 eggs to trigger the Boss to cast)
 Drill Cannons
              Drill CannonsDungeon
Magitek Vanguard H-2 - Level 50 Northern Thanalan (x16,y15)
Magitek Vanguard and Magitek Vanguard H-1 from Castrum Meridianum
Magitek Vangob G-III from Brayflox's Longstop (Hard)
 High Voltage
              High VoltageMasked Carnivale
Bestial Node from Stage 15 Masked Carnivale - The Me Nobody Nodes
 Loom
              LoomDungeon
Dantalion (Trash) & Phantom Knight (Trash) in Tam-Tara Deepcroft (Hard)
Baalzephon from The Lost City of Amdapor
 Final Sting
              Final StingDungeon
Temple Bee (Trash Before & After 1st Boss) from The Sunken Temple of Qarn
 Song of Torment
              Song of TormentOpen World
Aglaope - Rank S Elite Mark in Il Mheg
 Glower
              GlowerOpen World
Brontes - Rank S Elite Mark in Central Thanalan
 Plaincracker
              PlaincrackerDungeon
Masked Carnivale
Sandstone Golem - Level 29 Southern Thanalan (x24,y13)
Nunyunuwi - Rank S Elite Mark in Southern Thanalan
Basalt Golem - Level 34 Outer La Noscea (x16,y16)
Gogmagolem (2nd Boss) from Copperbell Mines (Hard)
Azulmagia from Stage 25 Masked Carnivale - Dirty Rotten Azulmagia
 Bristle
              BristleWild Boar - Level 20 East Shroud (x18,y24)
 White Wind
              White WindEnkidu from Battle in the Big Keep
 Level 5 Petrify
              Level 5 Petrify Sharpened Knife
              Sharpened KnifeDungeon
Tonberry King (Last Boss) from The Wanderer's Palace
 Ice Spikes
              Ice SpikesDungeon
Masked Carnivale
Vandalous Imp - Level 16 Eastern Thanalan (x15,y19)
Manor Jester (Second Boss) from Haukke Manor
Azulmagia from Stage 25 Masked Carnivale - Dirty Rotten Azulmagia
 Blood Drain
              Blood DrainDungeon
Cave Bat - Level 7 Lower La Noscea (x27,y16)
Sun Bat - Level 10-14 Central Thanalan (x26,y18)
Dusk Bat - Level 15 Western La Noscea (x27,y24)
Black Bat - Level 20-21 East Shroud (x17,y23)
Barbastelle - Rank B Elite Mark in Lower La Noscea
Attic Bat (Trash before 1st Boss) from Haukke Manor
Sand Bat - Level 38 Cutter's Cry
 Acorn Bomb
              Acorn BombTreant Sapling - Level 12-17 Central Shroud (x27,y15)
Treant Sapling - Level 14 East Shroud (x13,y25)
Wulgaru - Rank S Elite Mark in East Shroud
 Bomb Toss
              Bomb TossDungeon
Goblin Glider & Goblin Brandisher - Level 58 The Dravanian Hinterlands (x29,y23)
Slipkinx Steeljoints - Rank A Elite Mark in The Dravanian Hinterlands
Illuminati Commander from Brayflox's Longstop (Hard)
 Off-guard
              Off-guard Self-destruct
              Self-destructDungeon
Masked Carnivale
Blasting Cap from Copperbell Mines
Flambeau from Copperbell Mines
Gas Bomb from Halatali
Shrapnel from Cutter's Cry
Arena Cherry Bomb from Stage 8 Masked Carnivale - The Bomb-edy of Errors
 Transfusion
              Transfusion Faze
              FazeQiqirn Shellsweeper - Level 9 Central Thanalan (x16,y19)
Qiqirn Eggdigger - Level 13 Lower La Noscea (x18,y35)
Qiqirn Gullroaster in Careless Whiskers Level 30 FATE from Eastern La Noscea (x29,y34)
Qiqirn Gullroaster - Level 32 Eastern La Noscea (x26,y32)
 Flying Sardine
              Flying SardineBloody Mary - Rank B Elite Mark in Eastern La Noscea
 Snort
              SnortMasked Carnivale
Typhon from Stage 20 Masked Carnivale - Miss Typhon
Typhon from Stage 27 Masked Carnivale - Lock up Your Snorters
 4-tonze Weight
              4-tonze Weight The Look
              The LookDungeon
Raid
Anantaboga (Last Boss) from Amdapor Keep
Valefor from Labyrinth of the Ancients
Bibliolater from The Great Gubal Library (Hard)
 Bad Breath
              Bad BreathMasked Carnivale
Dungeon
Halitostroper - Level 31 Central Shroud (x15,y21)
Stroper - Level 34 South Shroud (x20,y28)
Reflective Rebekkah from Stage 19 Masked Carnivale - On a Clear Day You Can Smell Forever
Morbol from Aurum Vale
 Diamondback
              DiamondbackTrial
Horde Armored Dragon from The Steps of Faith
 Mighty Guard
              Mighty Guard Sticky Tongue
              Sticky TongueDungeon
Toxic Toad - Level 14 Central Thanalan (x27,y19)
Doomed Gigantoad in Doomed - Level 9 FATE in Western Thanalan (x24.5,y21.5)
Laughing Toad - Level 22 Western Thanalan (x15,y7)
Gigantoad - Level 33 Eastern La Noscea (x18,y26)
Bone Nix from Dzemael Darkhold (Unconfirmed, used in many dungeons after this)
 Toad Oil
              Toad Oil The Ram's Voice
              The Ram's VoiceOpen World
Trial
Raid
Masked Carnivale
Gorgimera in Go, Go, Gorgimera - Level 49 FATE in Northern Thanalan (x18,y13) (Will spawn massive number of adds)
Chimera from A Relic Reborn: The Chimera
Apademak from Stage 21 Masked Carnivale - Chimera on a Hot Tin Roof
Azulmagia from Stage 25 Masked Carnivale - Dirty Rotten Azulmagia
Shadowcourt Hound from Dun Scaith
Tyger - Rank S Elite Mark in Lakeland
 The Dragon's Voice
              The Dragon's VoiceOpen World
Trial
Raid
Masked Carnivale
Gorgimera in Go, Go, Gorgimera - Level 49 FATE in Northern Thanalan (x18,y13) (Will spawn massive number of adds)
Chimera from A Relic Reborn: The Chimera
Apademak from Stage 21 Masked Carnivale - Chimera on a Hot Tin Roof
Azulmagia from Stage 25 Masked Carnivale - Dirty Rotten Azulmagia
Shadowcourt Hound from Dun Scaith
Tyger - Rank S Elite Mark in Lakeland
 Missile
              MissileGuardian from Sigmascape V3.0
 1000 Needles
              1000 NeedlesDungeon
Sabotender Bailaor - Level 26 Southern Thanalan (x16,y15)
Sabotender Desertor from Cutter's Cry
 Ink Jet
              Ink Jet Fire Angon
              Fire Angon Moon Flute
              Moon Flute Tail Screw
              Tail ScrewOpen World
Raid
Reflection of Karlabos from Sirensong Sea
Crag Claw - Level 61 The Peaks (x25,y11)
Brutal Barber in Barbershoppe - Level 61 FATE in The Peaks (x23.3,y9.3)
Clay Claw from Alexander - The Arm of the Father
Pterygotus - Rank B Elite Mark in The Dravanian Hinterlands
 Mind Blast
              Mind BlastRaid
Open World
Blaster from Alexander - The Burden of the Son
Mindflayer - Rank S Elite Mark in South Shroud
 Doom
              DoomOpen World
Ixtab - Rank S Elite Mark in The Rak'tika Greatwood
 Peculiar Light
              Peculiar LightDungeon
Kurrea - Rank A Elite Mark in Mor Dhona
Surf Eft from Brayflox's Longstop
Hellbender (Second Boss) from Brayflox's Longstop
Loch Nanka - Level 69 The Lochs (x17,y20)
 Feather Rain
              Feather Rain Eruption
              Eruption Mountain Buster
              Mountain Buster Shock Strike
              Shock Strike Glass Dance
              Glass Dance Veil of the Whorl
              Veil of the Whorl Alpine Draft
              Alpine DraftOpen World
Griffin - Level 59 The Sea of Clouds (x36,y9)
True Griffin - Level 68 The Peaks (x27,y25)
Neckbreaker in Breakneck - Level 68 FATE in The Peaks (x27,y25)
Vochstein - Rank A Elite Mark in The Peaks
 Protean Wave
              Protean WaveRaid
Masked Carnivale
Living Liquid (Last Boss) from Alexander - The Arm of the Father
Shikigami of the Undertow from Stage 29 Masked Carnivale Red, Fraught, and Blue
 Northerlies
              NortherliesDungeon
Slate Yeti - Level 56 Coerthas Western Highlands (x17,y27)
Mirka - Rank A Elite Mark in Coerthas Western Highlands
Yeti from Snowcloak
 Electrogenesis
              ElectrogenesisDungeon
Hikagiri from Shisui of the Violet Tides
 Kaltstrahl
              KaltstrahlStrum Doll from Alexander - The Cuff of the Father
 Abyssal Transfixion
              Abyssal TransfixionDungeon
Ash from Haukke Manor (Hard)
Everlasting Bibliotaph from The Great Gubal Library (Fail the mechanic and summon the third set of mobs)
 Chirp
              ChirpApotamkin in A Long Way Down - Level 50 FATE in Sea of Clouds (x36,y33) (unconfirmed)
Squonk - Rank B Elite Mark in Sea of Clouds
Stolas - Rank A Elite Mark in The Dravanian Hinterlands
 Eerie Soundwave
              Eerie SoundwaveOpen World
Dungeon
Empuse - Level 59 Azys Lla (x29,y12)
Arioch (2nd Boss) from The Lost City of Amdapor
 Pom Cure
              Pom Cure Gobskin
              GobskinRaid
Alexandrian Hider & Alexandrian Slider from Alexander - The Breath of the Creator
 Magic Hammer
              Magic HammerEpilogi from Stage 24 Masked Carnivale - Amazing Technicolor Pit Fiends
 Avail
              Avail Frog Legs
              Frog LegsBero Roggo in Toad Alone - Level 59 FATE in The Dravanian Hinterlands (x12,y35)
 Sonic Boom
              Sonic BoomOpen World
Zu from Pharos Sirius
Anzu Crone in Anzu Trois Level 50 FATE in The Sea of Clouds (x30.0,y36.0)
Anzu - Level 59 The Sea of Clouds (x25,y6)
 Whistle
              WhistleDungeon
Jhammel - Level 68 The Peaks (x26.5,y28.5)
Nenaunir in Slaughterwife-five Level 68 FATE in The Peaks (x23,y30)
Dhalmel from Neverreap
 White Knight's Tour
              White Knight's Tour Black Knight's Tour
              Black Knight's Tour Level 5 Death
              Level 5 Death Launcher
              LauncherDungeon
Gamma - Rank S Elite Mark in Yanxia
Armored Weapon from Baelsar's Wall
Doman Armored Weapon from Doma Castle
 Perpetual Ray
              Perpetual Ray Cactguard
              Cactguard Revenge Blast
              Revenge Blast Angel Whisper
              Angel Whisper Exuviation
              ExuviationDungeon
Abalathian Wamoura - Level 57-58 The Sea of Clouds (x10,y17) (must damage a Window Wamouracampa in the fight first)
 Reflux
              Reflux Devour
              DevourDungeon
Raid
Yilan - Rank A Elite Mark in Thavnair
The Decaying Gourmand from The Lost City of Amdapor
Caduceus from The Binding Coil of Bahamut - Turn 1
Rafflesia from The Second Coil of Bahamut - Turn 1
Cerberus from World of Darkness
Nullchu from Saint Mocianne's Arboretum (Hard)
 Condensed Libra
              Condensed LibraMasked Carnivale
Arena Scribe from Stage 24 Masked Carnivale - Amazing Technicolor Pit Fiends
 Aetheric Mimicry
              Aetheric Mimicry Surpanakha
              Surpanakha Quasar
              Quasar J Kick
              J Kick Triple Trident
              Triple TridentEbisu Catfish - Level 67 Yanxia (x28,y6)
Gyorai Quickstrike - Rank B Elite Mark in Yanxia
 Tingle
              TingleEbisu Catfish - Level 67 Yanxia (x28,y6)
Gyorai Quickstrike - Rank B Elite Mark in Yanxia
 Tatami-gaeshi
              Tatami-gaeshi Cold Fog
              Cold Fog Stotram
              Stotram Saintly Beam
              Saintly Beam Feculent Flood
              Feculent FloodOpen World
The Mudman - Rank A Elite Mark in Il Mheg
 Angel's Snack
              Angel's Snack Chelonian Gate
              Chelonian Gate The Rose of Destruction
              The Rose of Destruction Basic Instinct
              Basic InstinctDungeon
Coeurl Smriti from Temple of the Fist
 Ultravibration
              UltravibrationGwas-y-neidr - Rank B Elite Mark in The Peaks
 Blaze
              Blaze Mustard Bomb
              Mustard Bomb Dragon Force
              Dragon Force Aetherial Spark
              Aetherial SparkLuminare - Rank A Elite Mark in The Lochs
Rusalka - Rank A Elite Mark in The Tempest
 Hydro Pull
              Hydro Pull Malediction of Water
              Malediction of Water Choco Meteor
              Choco Meteor Matra Magic
              Matra Magic Peripheral Synthesis
              Peripheral Synthesis Both Ends
              Both Ends Phantom Flurry
              Phantom Flurry Nightbloom
              NightbloomSource: https://ffxiv.consolegameswiki.com/wiki/Blue_Mage_Spells_Learning_Guide
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