How to Learn Moves as a Blue Mage
When you defeat an enemy after it has used that spell, you have a chance of learning it. Doing instances either premade with no Undersize options selected or with both Undersize and Level Sync options make the spell a 100% learn rate. Spell chances in the open world or Masked Carnivale are RNG based on the number of stars for that spell.
If you die before the enemy does you will not learn the spell. You must be alive as it dies in order to learn the spell. Killing an enemy with Self-destruct or Final Sting will result in failure to learn the spell.
Raid
Einhander from The Keeper of the Lake
Magitek Gunship from The Keeper of the Lake
Omega from Alphascape V3.0
Leviathan from The Whorleater (Hard), The Whorleater (Extreme)
Ultros from Stage 20 Masked Carnivale - Miss Typhon
Dungeon
Zu (2nd Boss) from Pharos Sirius (Kill 2 eggs to trigger the Boss to cast)
Dungeon
Magitek Vanguard H-2 - Level 50 Northern Thanalan (x16,y15)
Magitek Vanguard and Magitek Vanguard H-1 from Castrum Meridianum
Magitek Vangob G-III from Brayflox's Longstop (Hard)
Masked Carnivale
Bestial Node from Stage 15 Masked Carnivale - The Me Nobody Nodes
Dungeon
Dantalion (Trash) & Phantom Knight (Trash) in Tam-Tara Deepcroft (Hard)
Baalzephon from The Lost City of Amdapor
Dungeon
Temple Bee (Trash Before & After 1st Boss) from The Sunken Temple of Qarn
Open World
Aglaope - Rank S Elite Mark in Il Mheg
Open World
Brontes - Rank S Elite Mark in Central Thanalan
Dungeon
Masked Carnivale
Sandstone Golem - Level 29 Southern Thanalan (x24,y13)
Nunyunuwi - Rank S Elite Mark in Southern Thanalan
Basalt Golem - Level 34 Outer La Noscea (x16,y16)
Gogmagolem (2nd Boss) from Copperbell Mines (Hard)
Azulmagia from Stage 25 Masked Carnivale - Dirty Rotten Azulmagia
Wild Boar - Level 20 East Shroud (x18,y24)
Enkidu from Battle in the Big Keep
Dungeon
Tonberry King (Last Boss) from The Wanderer's Palace
Dungeon
Masked Carnivale
Vandalous Imp - Level 16 Eastern Thanalan (x15,y19)
Manor Jester (Second Boss) from Haukke Manor
Azulmagia from Stage 25 Masked Carnivale - Dirty Rotten Azulmagia
Dungeon
Cave Bat - Level 7 Lower La Noscea (x27,y16)
Sun Bat - Level 10-14 Central Thanalan (x26,y18)
Dusk Bat - Level 15 Western La Noscea (x27,y24)
Black Bat - Level 20-21 East Shroud (x17,y23)
Barbastelle - Rank B Elite Mark in Lower La Noscea
Attic Bat (Trash before 1st Boss) from Haukke Manor
Sand Bat - Level 38 Cutter's Cry
Treant Sapling - Level 12-17 Central Shroud (x27,y15)
Treant Sapling - Level 14 East Shroud (x13,y25)
Wulgaru - Rank S Elite Mark in East Shroud
Dungeon
Goblin Glider & Goblin Brandisher - Level 58 The Dravanian Hinterlands (x29,y23)
Slipkinx Steeljoints - Rank A Elite Mark in The Dravanian Hinterlands
Illuminati Commander from Brayflox's Longstop (Hard)
Dungeon
Masked Carnivale
Blasting Cap from Copperbell Mines
Flambeau from Copperbell Mines
Gas Bomb from Halatali
Shrapnel from Cutter's Cry
Arena Cherry Bomb from Stage 8 Masked Carnivale - The Bomb-edy of Errors
Qiqirn Shellsweeper - Level 9 Central Thanalan (x16,y19)
Qiqirn Eggdigger - Level 13 Lower La Noscea (x18,y35)
Qiqirn Gullroaster in Careless Whiskers Level 30 FATE from Eastern La Noscea (x29,y34)
Qiqirn Gullroaster - Level 32 Eastern La Noscea (x26,y32)
Bloody Mary - Rank B Elite Mark in Eastern La Noscea
Masked Carnivale
Typhon from Stage 20 Masked Carnivale - Miss Typhon
Typhon from Stage 27 Masked Carnivale - Lock up Your Snorters
Dungeon
Raid
Anantaboga (Last Boss) from Amdapor Keep
Valefor from Labyrinth of the Ancients
Bibliolater from The Great Gubal Library (Hard)
Masked Carnivale
Dungeon
Halitostroper - Level 31 Central Shroud (x15,y21)
Stroper - Level 34 South Shroud (x20,y28)
Reflective Rebekkah from Stage 19 Masked Carnivale - On a Clear Day You Can Smell Forever
Morbol from Aurum Vale
Trial
Horde Armored Dragon from The Steps of Faith
Dungeon
Toxic Toad - Level 14 Central Thanalan (x27,y19)
Doomed Gigantoad in Doomed - Level 9 FATE in Western Thanalan (x24.5,y21.5)
Laughing Toad - Level 22 Western Thanalan (x15,y7)
Gigantoad - Level 33 Eastern La Noscea (x18,y26)
Bone Nix from Dzemael Darkhold (Unconfirmed, used in many dungeons after this)
Open World
Trial
Raid
Masked Carnivale
Gorgimera in Go, Go, Gorgimera - Level 49 FATE in Northern Thanalan (x18,y13) (Will spawn massive number of adds)
Chimera from A Relic Reborn: The Chimera
Apademak from Stage 21 Masked Carnivale - Chimera on a Hot Tin Roof
Azulmagia from Stage 25 Masked Carnivale - Dirty Rotten Azulmagia
Shadowcourt Hound from Dun Scaith
Tyger - Rank S Elite Mark in Lakeland
Open World
Trial
Raid
Masked Carnivale
Gorgimera in Go, Go, Gorgimera - Level 49 FATE in Northern Thanalan (x18,y13) (Will spawn massive number of adds)
Chimera from A Relic Reborn: The Chimera
Apademak from Stage 21 Masked Carnivale - Chimera on a Hot Tin Roof
Azulmagia from Stage 25 Masked Carnivale - Dirty Rotten Azulmagia
Shadowcourt Hound from Dun Scaith
Tyger - Rank S Elite Mark in Lakeland
Guardian from Sigmascape V3.0
Dungeon
Sabotender Bailaor - Level 26 Southern Thanalan (x16,y15)
Sabotender Desertor from Cutter's Cry
Open World
Raid
Reflection of Karlabos from Sirensong Sea
Crag Claw - Level 61 The Peaks (x25,y11)
Brutal Barber in Barbershoppe - Level 61 FATE in The Peaks (x23.3,y9.3)
Clay Claw from Alexander - The Arm of the Father
Pterygotus - Rank B Elite Mark in The Dravanian Hinterlands
Raid
Open World
Blaster from Alexander - The Burden of the Son
Mindflayer - Rank S Elite Mark in South Shroud
Open World
Ixtab - Rank S Elite Mark in The Rak'tika Greatwood
Dungeon
Kurrea - Rank A Elite Mark in Mor Dhona
Surf Eft from Brayflox's Longstop
Hellbender (Second Boss) from Brayflox's Longstop
Loch Nanka - Level 69 The Lochs (x17,y20)
Open World
Griffin - Level 59 The Sea of Clouds (x36,y9)
True Griffin - Level 68 The Peaks (x27,y25)
Neckbreaker in Breakneck - Level 68 FATE in The Peaks (x27,y25)
Vochstein - Rank A Elite Mark in The Peaks
Raid
Masked Carnivale
Living Liquid (Last Boss) from Alexander - The Arm of the Father
Shikigami of the Undertow from Stage 29 Masked Carnivale Red, Fraught, and Blue
Dungeon
Slate Yeti - Level 56 Coerthas Western Highlands (x17,y27)
Mirka - Rank A Elite Mark in Coerthas Western Highlands
Yeti from Snowcloak
Dungeon
Hikagiri from Shisui of the Violet Tides
Strum Doll from Alexander - The Cuff of the Father
Dungeon
Ash from Haukke Manor (Hard)
Everlasting Bibliotaph from The Great Gubal Library (Fail the mechanic and summon the third set of mobs)
Apotamkin in A Long Way Down - Level 50 FATE in Sea of Clouds (x36,y33) (unconfirmed)
Squonk - Rank B Elite Mark in Sea of Clouds
Stolas - Rank A Elite Mark in The Dravanian Hinterlands
Open World
Dungeon
Empuse - Level 59 Azys Lla (x29,y12)
Arioch (2nd Boss) from The Lost City of Amdapor
Raid
Alexandrian Hider & Alexandrian Slider from Alexander - The Breath of the Creator
Epilogi from Stage 24 Masked Carnivale - Amazing Technicolor Pit Fiends
Bero Roggo in Toad Alone - Level 59 FATE in The Dravanian Hinterlands (x12,y35)
Open World
Zu from Pharos Sirius
Anzu Crone in Anzu Trois Level 50 FATE in The Sea of Clouds (x30.0,y36.0)
Anzu - Level 59 The Sea of Clouds (x25,y6)
Dungeon
Jhammel - Level 68 The Peaks (x26.5,y28.5)
Nenaunir in Slaughterwife-five Level 68 FATE in The Peaks (x23,y30)
Dhalmel from Neverreap
Dungeon
Gamma - Rank S Elite Mark in Yanxia
Armored Weapon from Baelsar's Wall
Doman Armored Weapon from Doma Castle
Dungeon
Abalathian Wamoura - Level 57-58 The Sea of Clouds (x10,y17) (must damage a Window Wamouracampa in the fight first)
Dungeon
Raid
Yilan - Rank A Elite Mark in Thavnair
The Decaying Gourmand from The Lost City of Amdapor
Caduceus from The Binding Coil of Bahamut - Turn 1
Rafflesia from The Second Coil of Bahamut - Turn 1
Cerberus from World of Darkness
Nullchu from Saint Mocianne's Arboretum (Hard)
Masked Carnivale
Arena Scribe from Stage 24 Masked Carnivale - Amazing Technicolor Pit Fiends
Ebisu Catfish - Level 67 Yanxia (x28,y6)
Gyorai Quickstrike - Rank B Elite Mark in Yanxia
Ebisu Catfish - Level 67 Yanxia (x28,y6)
Gyorai Quickstrike - Rank B Elite Mark in Yanxia
Open World
The Mudman - Rank A Elite Mark in Il Mheg
Dungeon
Coeurl Smriti from Temple of the Fist
Gwas-y-neidr - Rank B Elite Mark in The Peaks
Luminare - Rank A Elite Mark in The Lochs
Rusalka - Rank A Elite Mark in The Tempest
Source: https://ffxiv.consolegameswiki.com/wiki/Blue_Mage_Spells_Learning_Guide
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